This section of the Victron manual will help.
www.victronenergy.com
I suspect the jumper will be on by default but I'm not sure on which profile, probably the first (pin 1 to 2 bridged)
The first profile will essentially prioritise charging the Bluetti, so the LOAD terminal will be on until the leisure battery is essentially flat. The low voltage cutoff there is very low and you probably shouldn't rely on it if your leisure battery is lead acid.
The second profile will essentially prioritise the leisure battery so the LOAD terminal will only be on when the leisure battery is reasonably well charged and there is generation. That's probably the one to start with. AFAIK the algorithm for the LOAD terminal is driven entirely by battery voltage not by solar input, so I'd expect this to also switch on when your battery is being charged from the engine even if it's dark.
If you want finer control remove the jumper and you can do custom settings in the app.