Black option wire to the positive pole of the LiFePO4 100ah batteryCan you describe exactly how the two small "options" wires are connected?
Is that this section?
If so have you checked what voltages are at those points when you think it should be charging?
If you're confident from the test so far that the wiring and LB are sound, and 2 units behave the same, it sounds more like a configuration issue (so both units do not see the correct conditions to charge)
Red option wire routed to my fuse box and doubled up with the window washer fuse. I checked and it gets power.
Checked absolutely everything a million times but the brand new Ctek and the other borrowed one act exactly the same, they charge with solar no problem and the battery takes (from a mains charger) and gives a charge.