Currently with a basic split charge your leisure battery is only going to be charged to about 80% from the engine as that capacity is left for regenerative braking on the 6.1 Start Stop system.
Switching to a DC-DC charger will add that additional 20%, which can be significant given you really shouldn't take an AGM regularly under the 40-50% region.
As you have the solar start with that, especially if it's mostly summer use. If you need more of an edge you can add DC-DC later.
At the currents batteries and chargers operate at it's best to avoid using more than one cable in the terminal as often they are sized optimally for the high current cable. When you start your van after a few days off grid and the very low leisure battery is ganged with the starter battery by the relay you will get significant current flow and you don't want an area of high resistance in your distro board. If there are additional free connectors on some sort of bus bar those could be used.
Looking at the instructions your distro board seems to use bolt terminals like a battery post. They may take two connections, but I would expect with the heavy guage cable there two connectors may splay apart like a V as the bolt is tightened and get uncomfortably close to the neighbouring terminal. Have a look with the cover off to see what your cable looks like.
If not you should be able to mount a bus bar (or maybe even a single post) very nearby and add a short ready made battery cable from there into your distribution board and move the existing cables and your MPPT cables to the bus bar.
Power posts & busbars, cable jointing boxes and power distribution boxes with fuses. For use in cars, vans, trucks, motohomes, horseboxes, boats etc from 12 Volt Planet
www.12voltplanet.co.uk