1- yes thats fine going to the busbar (you should remove the fuse from the starter battery feed to shut down the dc-dc and also disconnect the PV POS from the MPPT side - that will switch off all power going to the LB and make there disconnected terminals safe (its always good practice to fully insulate any disconnected terminals anyway))
2- the MPPT is putting out power on the BATTERY terminals. when the sun is out (Disconnect the PV POS to shut it down) - that power is connected to the POS Busbar so feeding power into the leisure side of the system. - thats why the sockets are powered up.
The LOAD terminals on the MPPT can be used as a lov voltage cut off - if the 12v for the lights and sockets etc were taken from that terminal.
but are subject to the max throughput of the mppt (thats 15A for a 75/15 mppt)
but you haven't got them connected that way so not relevent in your setup.
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there is also the possibility that the CTEK and Vic MPPT are detecting each others 12v output and assuming its the 12v from the LB 9which has been removed)
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so if future if you need to remove the LB from under the seat . .
remove the main fused feeding the DC-DC at the starter battery and disconnect the PV POS from the MPPT - that will shut down all charging power going to the LB
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