It would appear not. I’ve just taken delivery of a new campervan based on a LWB 204PS 4Motion Highline PV built on 29 March this year, with a factory fitted second battery installed under the passenger seat. Having measured the voltage at both these sockets at 13.6V when on EHU, whilst the starter battery reads 12.5V, it appears BOTH 12V sockets in the cab are powered by the second battery.
I was hoping to keep the starter battery topped up by connecting a CTEK battery conditioner to the lower socket and fed from the internal mains socket and leave the van hooked up to the mains via the EHU. Unfortunately, in my case this doesn’t look like it’ll work as neither of the 12V sockets appear to be fed from the starter battery and I’ll have to find another feed from the starter battery (probably from under the passenger seat). It seems that VW has changed things.