DC-DC won’t over ride the solar, any output from them will combine (e.g. 18A Orion and 5A MPPT should show as 23A on the shunt (and Fogstar app) minus any load.
Do you have an isolation switch between your solar panel and MPPT? If so switch it off so you can focus on DC-DC and shunt to start with. I have a feeling the MPPT may have itself in a tiss, likely because at one stage the LB has been disconnected from it while the panel was producing power - the panel should always be disconnected first, or connected last.
Second, there is still something not quite right with the wiring. Particularly the shunt. Is the little red wire from it to the LB properly connected and the fuse holder done up properly?
Finally, make sure both Orion and MPPT are set to the correct parameters for the LB. Either start with the smart lithium preset or use a custom one with the settings given on the Fogstar FAQ page.